Новый путь к синтезу хиральных 1,2,4-оксадиазин-5-онов: Prostoj sintez nowyh hiral'nyh 1,2,4-oxadiazin-5-onow iz prirodnyh aminokislot
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Затем они реагируют с тионилхлоридом и метанолом, получая соответствующие α-бромоэфиры. Конденсация этих ранее приготовленных α-бромоэфиров с 1-бензолсульфонилпирролидин-2-карбоксамидоксимом в присутствии двух эквивалентов гидрида натрия позволила получить новые хиральные 1,2,4-оксадиазин-5-оны с хорошими химическими выходами.
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