Nouvelle voie de synthèse de 1,2,4-oxadiazin-5-ones chirales: synthèse facile de nouvelle 1,2,4-oxadiazin-5-ones chirales à partir des acides aminés naturels
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Ces derniers vont réagir par la suite avec le chlorure de thionyle suivie du méthanol pour donner des α-bromoesters correspondants. La condensation de ces α-bromoesters préparés précédemment avec le 1-benzéne-sulfonylpyrrolidin-2-carboxamidoxime en présence de deux équivalents d'hydrure de sodium offre des nouvelles 1,2,4-oxadiazin-5-ones chirales désirés avec des bons rendements chimiques.
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£27.18
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